Eco-friendly Approach for Effective Sorption of Congo Red Dye from Aqueous Solution Using NiAl LDH@DICD
DOI:
https://doi.org/10.63635/mrj.v1i1.7Keywords:
Layered Double Hydroxides, Adsorption, Dillenia Indica, Carbon Dots, Congo Red DyeAbstract
Congo red dye, a prominent pollutant widely utilized in the textile industry, bestows significant challenges to environmental health and the aquatic ecosystems. In this study, we present a constructive approach through the development of a novel hybrid adsorbent, NiAl LDH@DICD, synthesized via simple co-precipitation method. This innovative material effectively combines pristine NiAl LDH with carbon dots derived from Dillenia Indica, leading to substantial improvements in dye removal efficiency while ensuring enhanced structural stability and reusability. Various characterization analyses provide confirmation of the successful synthesis and integration of carbon dots within the NiAl LDH matrix. High-Resolution Transmission Electron Microscopy (HRTEM) offers clear visual evidence of this incorporation, while photoluminescence (PL) study confirm the structural stability of the NiAl LDH@DICD. This robustness is vital for ensuring the adsorbent maintains its performance during repeated use. To assess the performance of NiAl LDH@DICD in removing Congo red dye from contaminated water, we carried out comprehensive batch equilibrium adsorption studies. The results highlighted that it follows the Freundlich isotherm model, indicating a heterogeneous multilayer adsorption process, achieving an R² value of 0.99. Notably, our adsorbent material achieved a dye removal efficiency of 87%, reflecting its considerable adsorption capacity even after three cycles of reuse. This research not only demonstrates the effectiveness of NiAl LDH@DICD as a reusable adsorbent for dye removal but also highlights its potential for sustainable applications in environmental remediation and also for heavy metal removal. The findings pave the way for further research aimed at advancing solutions for water treatment and pollution management, contributing to the development of more effective strategies for maintaining water quality.
References
[1] Alsukaibi, A.K. Various approaches for the detoxification of toxic dyes inwastewater. Processes 2022, 10, 1968, https://doi.org/10.3390/pr10101968
[2] Roy Choudhury, A.K. Green chemistry and the textileindustry. Textile Progress 2013, 45, 3-143, https://doi.org/10.1080/00405167.2013.807601.
[3] Ahmad, A.; Mohd-Setapar S.H.; Chuong, C.S.; Khatoon, A; Wani, W.A.; Kumar, R., Rafatullah, M. Recent advances in new generation dye removal technologies: novel search for approaches to reprocess wastewater. RSC Adv. 2015, 5, 30801-18,https://doi.org/10.1039/C4RA16959J
[4] Zhou, Y.; Lu, J.; Zhou, Y.; Liu, Y. Recent advances for dyes removal using novel adsorbents: a review. Environmental pollution. 2019, 252, 352-65. https://doi.org/10.1016/j.envpol.2019.05.072
[5] Islam, T.; Repon, M.R.; Islam, T.; Sarwar, Z.; Rahman, M.M. Impact of textile dyes on health and ecosystem: A review of structure, causes, and potential solutions. ESPR 2023, 30, 9207-42. https://doi.org/10.1007/s11356-022-24398-3
[6] Ramamurthy, K.; Priya, P.S.; Murugan, R.; Arockiaraj, J. Hues of risk: investigating genotoxicity and environmental impacts of azo textile dyes. ESPR 2024, 27, 1-22, https://doi.org/10.1007/s11356-024-33444-1
[7] Jadhav, A.C.; Jadhav, N.C. Treatment of textile wastewater using adsorption and adsorbents. InSustainable technologies for textile wastewater treatments 2021 (pp. 235-273). Woodhead Publishing. https://doi.org/10.1016/B978-0-323-85829-8.00008-0
[8] Belay, A. MORINGA OLEIFERAAS ALTERNATIVE LOW COST BIOCOAGULANT FOR REMOVAL OF REACTIVE DYE FROM TEXTILE EFFLUENT (Doctoral dissertation).
[9] Singh, K.; Arora, S. Removal of synthetic textile dyes from wastewaters: a critical review on present treatment technologies. Critical reviews in environmental science and technology 2011, 41, 807-78. https://doi.org/10.1080/10643380903218376
[10] Zhang, M.; Biesold, G.M.; Choi, W.; Yu, J.; Deng, Y.; Silvestre, C.; Lin, Z. Recent advances in polymers and polymer composites for food packaging. Mater. Today. 2022, 53, 134-61. https://doi.org/10.1016/j.mattod.2022.01.022
[11] Ahmaruzzaman, M. Industrial wastes as low-cost potential adsorbents for the treatment of wastewater laden with heavy metals. Adv. Colloid Interface Sci. 2011, 166, 36-59. https://doi.org/10.1016/j.cis.2011.04.005
[12] Çeçen, F.; Aktas, Ö. Activated carbon for water and wastewater treatment: integration of adsorption and biological treatment. John Wiley & Sons; 2011.
[13] Isaeva, V,I.; Vedenyapina, M.D.; Kurmysheva, A.Y.; Weichgrebe, D.; Nair, R.R.; Nguyen, N.P.; Kustov, L.M. Modern carbon-based materials for adsorptive removal of organic and inorganic pollutantsFrom water and wastewater. Molecules 2021 26, 6628 https://doi.org/10.3390/molecules26216628
[14] Lancaster, M. 2020.Green chemistry:anintroductory text.Royalsocietyofchemistry.
[15] Wilson, M.P.; Schwarzman, M.R. Toward a new US chemicals policy: rebuilding the foundation to advance new science, green chemistry, and environmental health. EHP 2009, 117, 1202-9. https://doi.org/10.1289/ehp.0800404
[16] Wareing, T.C.; Gentile, P.; Phan, A.N. Biomass-based carbon dots: current development and future perspectives. ACS nano. 2021, 15, 15471-501. https://doi.org/10.1021/acsnano.1c03886
[17] Gaurav, A.; Jain, A.; Tripathi, S.K. Review on fluorescent carbon/graphene quantum dots: promising material for energy storage and next-generation light-emitting diodes. Materials. 2022, 15, 7888. https://doi.org/10.3390/ma15227888
[18] Hola, K.; Bourlinos, A.B.; Kozak, O.; Berka, K.; Siskova, K.M.; Havrdova, M.; Tucek, J.; Safarova, K.; Otyepka, M.; Giannelis, E.P.; Zboril, R. Photoluminescence effects of graphitic core size and surface functional groups in carbon dots: COO− induced red-shift emission. Carbon 2014,
70, 279-86. https://doi.org/10.1016/j.carbon.2014.01.008
[19] Bhattacharya, D.; Mishra, M.K.; De, G. Carbon dots from a single source exhibiting tunable luminescent colors through the modification of surface functional groups in ORMOSIL films. J. Phys. Chem. C 2017, 121, 28106-16. https://doi.org/10.1021/acs.jpcc.7b08039
[20] Shi, W.; Guo, F.; Wang, H.; Liu, C.; Fu, Y.; Yuan, S.; Huang, H.; Liu, Y.; Kang, Z. Carbon dots decorated magnetic ZnFe2O4 nanoparticles with enhanced adsorption capacity for the removal of dye from aqueous solution. Appl Surf Sci 2018, 433, 790-7. https://doi.org/10.1016/j.apsusc.2017.10.099
[21] Sahoo, T.R.; Prelot, B. Adsorption processes for the removal of contaminants from wastewater: the perspective role of nanomaterials and nanotechnology. InNanomaterials for the detection and removal of wastewater pollutants 2020, (pp. 161-222). Elsevier. https://doi.org/10.1016/B978-0-12-818489-9.00007-4
[22] Yu, J.; Liu, C.; Yuan, K.; Lu, Z.; Cheng, Y.; Li, L.; Zhang, X.; Jin, P.; Meng, F.; Liu, H. Luminescence mechanism of carbon dots by tailoring functional groups for sensing Fe3+ ions. Nanomaterials. 2018, 8, 233, https://doi.org/10.3390/nano8040233
[23] Schneider, J.; Reckmeier, C.J.; Xiong, Y.; von Seckendorff, M.; Susha, A.S.; Kasák, P.; Rogach, A.L. Molecular fluorescence in citric acid-based carbon dots. J. Phys. Chem. C 2017, 121, 2014-22, https://doi.org/10.1021/acs.jpcc.6b12519
[24] Chen, B.B.; Liu, M.L.; Li, C.M.; Huang, C.Z. Fluorescent carbon dots functionalization. Adv. Colloid Interface Sci 2019, 270, 165-90, https://doi.org/10.1016/j.cis.2019.06.008
[25] Wang, Q.; Zheng, H.; Long, Y.; Zhang, L.; Gao, M.; Bai, W. Microwave–hydrothermal synthesis of fluorescent carbon dots from graphite oxide. Carbon 2011, 49, 3134-40, https://doi.org/10.1016/j.carbon.2011.03.041
[26] Tuerhong, M.; Yang, X.U.; Xue-Bo, Y.I. Review on carbon dots and their applications. Chin. J. Anal. Chem. 2017, 45, 139-50, https://doi.org/10.1016/S1872-2040(16)60990-8
[27] Meng, W.; Bai, X.; Wang, B.; Liu, Z.; Lu, S.; Yang, B. Biomass‐derived carbon dots and their applications. EEM 2019, 2, 172-92, https://doi.org/10.1002/eem2.12038
[28] Anantharaj, S.; Karthick, K.; Kundu, S. Evolution of layered double hydroxides (LDH) as high performance water oxidation electrocatalysts: A review with insights on structure, activity and mechanism. Mater Today Energy 2017, 6, 1-26, https://doi.org/10.1016/j.mtener.2017.07.016
[29] Yang, Z.; Wang, F.; Zhang, C.; Zeng, G.; Tan, X.; Yu, Z.; Zhong, Y.; Wang, H.; Cui, F. Utilization of LDH-based materials as potential adsorbents and photocatalysts for the decontamination of dyes wastewater: a review. RSC Adv. 2016, 6, 79415-36, https://doi.org/10.1039/C6RA12727D
[30] Saikia, H. Coconut Husk Ash Fabricated CoAl-Layered Double Hydroxide composite for the enhanced sorption of Malachite green dye: Isotherm, Kinetics and Thermodynamic studies. Kinetics and Thermodynamic Studies. 2022. https://doi.org/10.1016/j.inoche.2022.109878
[31] Saikia, H.; Ganguli, J.N. Intercalation of azo dyes in ni-al layered double hydroxides. Asian J. Chem. 2012, 24, 5909.
[32] Brahma, D.; Saikia, H. Synthesis of ZrO2/MgAl-LDH composites and evaluation of its isotherm, kinetics and thermodynamic properties in the adsorption of Congo red dye. Chem. Thermodyn. Therm. Anal. 2022, 7, 100067, https://doi.org/10.1016/j.ctta.2022.100067
[33] Brahma, D.; Saikia, H. Surfactants assisted synthesis of CuAl-sodium dodecyl sulfate layered double hydroxide and its adsorptive removal of methyl red dye from aqueous solution. INORG NANO-MET CHEM. 2023, 13, 1-6, https://doi.org/10.1080/24701556.2023.2166074
[34] Brahma, D.; Nath, K.P.; Patgiri, M.; Saikia, H. Synthesis of ternary CaNiAl-layered double hydroxide as potential adsorbent for Congo red dye removal in aqueous solution. Asian J Chem. 2022, 34, 3215-23.
[35] Zhang, M.; Yao, Q.; Lu, C.; Li, Z.; Wang, W. Layered double hydroxide–carbon dot composite: high-performance adsorbent for removal of anionic organic dye. ACS Appl. Mater. Interfaces 2014, 6, 20225-33, https://doi.org/10.1021/am505765e
[36] Ge, J.; Lian, L.; Wang, X.; Cao, X.; Gao, W.; Lou, D. Coating layered double hydroxides with carbon dots for highly efficient removal of multiple dyes. J. Hazard. Mater 2022, 424, 127613. https://doi.org/10.1016/j.jhazmat.2021.127613
[37] Ding, P.; Song, H.; Chang, J.; Lu, S. N-doped carbon dots coupled NiFe-LDH hybrids for robust electrocatalytic alkaline water and seawater oxidation. Nano Research. 2022, 15, 7063-70, https://doi.org/10.1007/s12274-022-4377-4
[38] Wang, L.; Chen, X.; Liu, C.; Yang, W. Non-enzymatic acetylcholine electrochemical biosensor based on flower-like NiAl layered double hydroxides decorated with carbon dots. SENSOR ACTUAT B-CHEM, 2016, 233, 199-205, https://doi.org/10.1016/j.snb.2016.04.062
[39] Lv, Z.; Yang, S.; Zhu, H.; Chen, L.; Alharbi, N.S.; Wakeel, M.; Wahid, A.; Chen, C. Highly
efficient removal of As (V) by using NiAl layered double oxide composites. Appl Surf Sci 2018, 448, 599-608, https://doi.org/10.1016/j.apsusc.2018.04.162
[40] Huang, W.; Yu, X.; Li, D. Adsorption removal of Congo red over flower-like porous microspheres derived from Ni/Al layered double hydroxide. RSC Adv. 2015, 5, 84937-46, https://doi.org/10.1039/C5RA13922H
[41] Palapa, N.R.; Taher, T.; Normah, N.; Lesbani, A. NiAl layered double hydroxide/rice husk composite for the efficient removal of malachite green. Indones. J. Chem 2022, 22, 142-56, https://doi.org/10.22146/ijc.68021
[42] Siregar, P.M.; Palapa, N.R.; Wijaya, A.; Fitri, E.S.; Lesbani, A. Structural stability of Ni/Al layered double hydroxide supported on graphite and biochar toward adsorption of congo red. Sci. technol. Indones. 2021, 6, 85-95, https://doi.org/10.26554/sti.2021.6.2.85-95
Downloads
Published
Issue
Section
License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Copyright © Author(s) retain the copyright of this article.
How to Cite
Similar Articles
- Dipanwita Basak, Hemaprobha Saikia, Biosorption of crystal violet by B/nZVCu-Zn nanoparticles using Lawsonia inermis in aqueous medium , Multidisciplinary Research Journal: Volume 1, Issue 2, 2025
- Moon Mandal, Archana Deka, Viveeyan Saikia, Nano-composites based on Chitin for the Removal of Heavy Metals from Wastewater: A Mini Review , Multidisciplinary Research Journal: Volume 1, Issue 2, 2025
- Anurag Jayswal, Kabita Devi, Bhabesh Deka, Deepeshwar Singh, Ramesh C Deka, Suvendra Kumar Ray, A Longitudinal Single Case Study on Short-Duration Mind-Body Relaxation and Rejuvenation Technique Inspired from Ancient Mālā Japa , Multidisciplinary Research Journal: Volume 1, Issue 1, 2025
- Muzammill Ahmed, PredictiveControl BasedMPPT for Solar Boost Converters to Optimize Performance Under Fluctuating Irradiation and Loads , Multidisciplinary Research Journal: Volume 1, Issue 2, 2025
- Shagufta Rizwana, Manuj Kumar Hazarika, Near Infrared Spectroscopy and Machine Learning for Non-Destructive Estimation of Ageing of Komal Chaul , Multidisciplinary Research Journal: Volume 1, Issue 2, 2025
You may also start an advanced similarity search for this article.